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Ceramic Materials

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Boron Nitride BN
Boron Nitride
Boron nitride is a non-toxic, heat-resistant and chemically resistant compound with high resistivity and low density. It usually appears as colorless crystals or white powder. As an advanced ceramic material, boron nitride has a unique structure, which makes its performance similar to that of graphite and diamond, thus earning titles such as “white graphene” or “inorganic graphite”. Boron nitride has a wide range of applications and excellent physical properties, and has been widely studied and applied in various industries such as electronics and cosmetics. This article will explore its properties, density, structure, production methods and applications.
Material Advantages
To make solid shapes, hexagonal Boron Nitride (hBN) powders and binders are hot-pressed into billets up to 490mm x 490mm x 410mm at pressures up to 2000 psi and temperatures up to 2000°C. This process forms a material that is dense and easily machined and ready to use. It is available in virtually any custom shape that can be machined and has unique characteristics and physical properties which make it valuable for solving tough problems in a wide range of industrial applications.

  • Excellent thermal shock resistance
  • High electrical resistivity – excluding aerosols, paints, and ZSBN grade
  • Low density
  • High thermal conductivity
  • Anisotropic (thermal conductance differs between parallel and perpendicular planes to pressing direction)
  • Corrosion resistant
  • Good chemical inertness
  • High temperature material
  • Non-wetting
  • High dielectric breakdown strength, >40 KV/mm
  • Low dielectric constant, k=4
  • Excellent machinability
Purity Grades
PCBN1000
PCBN3000
PCBN6000
PCBN11000
Grade AX05
General Properties
PCBN1000 is a hot-pressed boron nitride, engineered to work in the most demanding applications. This high purity material is designed to exhibit low thermal expansion while having superb thermal shock properties.

PCBN1000 is easily machinable, has an excellent thermal conductance, very low thermal cycling behavior in use, and has good chemical resistivity to molten metal and glass. The lubricity of the material enables low frictional values even at elevated temperatures. It is also an electrical insulator with high dielectric strength and electrical resistivity.

PCBN1000 is ideal for high temperature applications that require boron nitride with minimal binder. It can be made up to 300mm in diameter and 300mm in length.
Applications
  • Electric propulsion discharge channels for Hall Effect Thrusters
  • Setter plates for high temperature furnaces
  • Crucibles for molten glass and metals
  • Electrical insulators for high temperatures and high voltages
  • Plasma chamber lining and fittings
  • Nozzles for non-ferrous metals and alloys
  • Thermocouple protection tubes and sheaths
  • Laser supports
General Properties
PCBN3000 is a unique hot-pressed boron nitride, engineered to work in the most demanding applications. This high purity material exhibits very low thermal expansion with superb thermal shock properties.

Binder-free PCBN3000 is the lowest hardness hexagonal Boron Nitride (hBN). It is easily machinable to very tight tolerances, has excellent thermal conductivity, very low thermal cycling behavior, and good chemical resistivity to molten metals at very high temperatures. The lubricity of the material enables low frictional values. It is non-reactive with graphite and refractory metals in the 2000°C range.

PCBN3000 is also an electrical insulator with high dielectric strength and electrical resistivity at extreme temperatures. PCBN3000 is ideal for high temperature applications that require boron nitride with no binder. It can be machined in large parts from billets up to 490mm x 490mm x 400mm.
Applications
Setter plates for high temperature furnacesCrucibles for non-oxide ceramics, phosphors, and metalsElectrical insulation for extremely high temperatures and high voltagesComponents exposed to molten saltsHall Effect Thruster insulatorsNozzles for non-ferrous metals and alloysThermocouple protection tubes and sheathsLaser supports
General Properties
PCBN6000 is an isotropic porous pure boron nitride, with high temperature capability, low thermal expansion, good lubrication and thermal shock properties. It is an electrical insulator with high dielectric strength at extreme temperatures. It can be machined into shapes up to 420 x 440 x 100mm.
Applications
Setter plates for high temperature furnacesCrucibles for non-oxide ceramics, phosphors, and metalsElectrical insulation for extremely high temperatures and high voltagesHall Effect Thruster insulatorsThermocouple protection tubes and sheaths
General Properties
PCBN11000 is a hot-pressed pure boron nitride, with high temperature capability, very low thermal expansion, good lubrication, and superb thermal shock properties. It is an electrical insulator with high dielectric strength and electrical resistivity at extreme temperatures.
Applications
  • Setter plates for high temperature furnaces
  • Crucibles for non-oxide ceramics, phosphors, and metals
  • Electrical insulation for extremely high temperatures and high voltages
  • Hall Effect Thruster insulators
  • Thermocouple protection tubes and sheaths
General Properties
Boron Nitride Grade AX05 is one of the highest purity hexagonal boron nitride (hBN) solids available. It is a good choice for applications where corrosion resistance is more important than wear resistance. It is a diffusion-bonded ceramic and does not depend on B2O3 or other binders for mechanical integrity. Consequently, it is non-wet by almost all molten metals. This ultra purity advantage allows for applications that are not provided by other hot pressed boron nitride solids, such as crucibles for high-purity molten metals. It is commonly used in applications that demand very high thermal conductivity such as nozzles with small orifices.

Key Properties

Chemically
Grade AX05 is extremely inert and non-wet by many molten materials such as metals, glasses, halide salts, and other reagents. The chemical stability allows Grade AX05 to provide a stable, non-reactive material for nozzles, feed-throughs, crucibles, and supports.
Thermally
Grade AX05 has minimal thermal expansion, high thermal conductivity, and use temperature in certain inert atmospheres over 2000°C. Thermal shock stability is excellent over a wide range of use temperatures.
Mechanically
Grade AX05 yields increasing relative strength versus temperature. This important feature provides higher temperature performance to applications previously unattainable with B2O3 and other bonded boron nitrides.
Electrically
Grade AX05 is transparent to microwave energy. It also provides high resistivity and dielectric strength with a low loss tangent and dielectric constant. These characteristics make AX05 an excellent material for high-power low-loss insulators, containers, and fixtures.
Machinability
Grade AX05 can be machined to extremely close tolerances using standard high speed “tool steel” equipment. Machining by grinding may be used if preferred or stringent tolerances are required. Threads can be machined using taps and dies. Cutting oils and coolants should not be used for any reason.
Applications
  • High temperature electrical insulators and vacuum furnace supports which require electrical resistivity, high temperature strength, thermal shock resistance, and low chemical reactivity
  • Crucibles and containers for high purity molten metals
  • lnsulators and source fixtures for ion implantation systems which require high temperature purity and electrical insulation
  • Setter plates for the processing of other advanced materials which require stable, inert surfaces
  • Nozzles for powdered metal spraying
Binder / Composite Grades
PCBN1000
PCBN4000
PCBN5000
PCBN9000
Grade A
Grade HP
Grade M/M26
General Properties
PCBN2000 is a hot-pressed boron nitride/silica composite, delivering excellent dielectric performance and insulation. This material has excellent thermal shock resistance while delivering low thermal expansion.
PCBN2000 is easily machined and has good flexural strength for a boron nitride.
Applications
  • Electric propulsion discharge channels for Hall Effect Thrusters
  • Plasma/corona insulators
  • Plasma constraints in PVD systems
  • Wear and corrosion resistance
  • Ultra high vacuum insulators
General Properties
PCBN4000 is a unique hot-pressed boron nitride, engineered to work in the most demanding applications. This stronger and harder Boron Nitride grade exhibits low thermal expansion with superb thermal shock properties.

PCBN4000 is the economical workhorse grade of hexagonal Boron Nitride. It is easily machinable to very tight tolerances, has good thermal conductivity, very low thermal cycling behavior, and chemical resistivity to molten metals to over 1000°C. The lubricity of the material enables low frictional values.

The properties of PCBN4000 are ideal for where the strength of the calcium borate glass binder is needed. It can be machined in large parts from billets up to 490mm x 490mm x 400mm.

PCBN4000 is also an electrical insulator with outstanding properties, retaining high dielectric strength and electrical resistivity up to 1000°C.
Applications
  • Setter plates for furnaces
  • Crucibles for non-oxide ceramics, phosphors, and metals
  • Electrical insulation for high temperatures and high voltages
  • Components exposed to molten salts
  • Nozzles for non-ferrous metals and alloys
  • Thermocouple protection tubes and sheaths
General Properties
PCBN5000 is a hot-pressed boron nitride, engineered to work in the most demanding applications. It is the combination of properties, along with its machinability, that makes this such a versatile and valuable grade.

This unique grade of hexagonal Boron Nitride (hBN) consists of high purity BN crystals bonded in a silica matrix. This gives it a moisture resistance that other Boron Nitride grades do not possess. It is easily machinable to very tight tolerances.

PCBN5000’s relatively high fracture toughness comes from its ability to deflect crack propagation. In addition, similar to silica glasses, it can exceed its stated temperature range for short periods of time. It won’t thermal shock. And if brought back down, its shape and properties will be maintained. It can be machined in large parts from billets up to 490mm x 490mm x 400mm.

PCBN5000 is also an electrical insulator with outstanding dielectric and microwave properties, retaining high dielectric strength and electrical resistivity up to 1000C.
Applications
  • Microwave components
  • Electrical insulation for high temperatures and high voltages
  • Hall Effect Thruster insulators
General Properties
Grade PCBN9000 with Calcium Borate binder has good mechanical and thermal properties, low thermal expansion, excellent thermal shock resistance, and strong electrical properties. Grade PCBN9000 is ideal for light metal processing, casting nozzles, PVD coating, and solder pads for example.
Applications
  • Electrical insulation for high temperatures
  • PVD Frames
  • Rada Components
  • Setter Plates
  • Spaying, Welding Nozzles
General Properties
Boron Nitride is an excellent choice for all but the most severe refractory applications. It is a high performance material possessing a glassy B2O3 binder that creates a hard and dense but fully machinable material.

Grade A is the oldest form of hot-pressed Boron Nitride. Specified into applications 50+ years ago, Grade A still finds a substantial replacement business as relatively high-temperature insulators in legacy semiconductor equipment and defense applications. Components up to 410mm x 495mm x 245mm can be produced. However, its B2O3 binder is hygroscopic and care must be taken to ensure components are isolated from moisture during storage and use. Precision Ceramics uses many methods of packaging to maintain the high quality of its machined components.
Applications
  • High temperature electrical insulators and vacuum furnace supports which require electrical resistivity, high temperature strength, thermal shock resistance, and low chemical reactivity
  • Crucibles and containers for high purity molten metals
  • Insulators and source fixtures for ion implantation systems which require high temperature purity and electrical insulation
  • Radar components and antenna windows which require exacting electrical and thermal properties
  • Setter plates for the processing of other advanced materials which require stable, inert surfaces
  • Nozzles for powdered metal spraying
General Properties
Grade HP is the workhorse grade of Boron Nitride. It is useful when low thermal expansion, high thermal shock resistance, and strong electrical properties are required. Grade HP was developed with a calcium borate glass binder in order to minimize the moisture issues of Grade A. It is available in sizes up to 410mm x 495mm x 245mm. It finds many diverse applications with its excellent machinability and maximum use temperature over 1000°C in inert or vacuum atmospheres.
Boron Nitride Grade HP is a superior solid grade for formulations of less than 1000°C. Additionally, Grade HP has ten times the moisture resistance of Grade A. It is commonly used for many light metal applications such as Al, Ti, Mg, and Zn.

Key Properties
Chemically
Grade HP has high corrosion resistance due to the addition of boron nitride. It has ten times the moisture resistance of other boron nitride solids due to the addition of calcium, which combines with boric oxide to form calcium borate.
Thermally
Excellent thermal shock resistance and conductivity – commonly used in many light metal applications such as Al, Ti, Mg, and Zn.
Electrically
Low dielectric constant material – also commonly used in many high temperature insulators.
Machinability
Like other grades of Boron Nitride, Grade HP can be machined using standard high speed ‘tool steel’ equipment. Machining by grinding may be used if preferred or stringent tolerances are required.
Applications
  • High temperature electrical insulators and vacuum furnace supports which require electrical resistivity, high temperature strength, thermal shock resistance, and low chemical reactivity
  • Crucibles and containers for high purity molten metals
  • Insulators and source fixtures for ion implantation systems which require high temperature purity and electrical insulation
  • Radar components and antenna windows which require stringent electrical and thermal properties
  • Setter plates for the processing of other advanced materials which require stable, inert surfaces
  • Nozzles for powdered metal spraying
General Properties
Solid Boron Nitride Grade M/M26 is a hydrophobic advanced ceramic. Composed of boron nitride and silica, it is completely resistant to moisture. This grade has successfully passed MIL-I-10A grade of L542 test, which is a procedure requiring immersion in water for 48 hours prior to testing at elevated frequencies. Grade M/M26 is suitable for the most severe electrical applications. It is an excellent refractory material at temperatures up to 1400°C and is unparalleled in resistance to thermal shock.
Applications
  • High temperature electrical insulators and vacuum furnace supports which require electrical resistivity, high temperature strength, thermal shock resistance, and low chemical resistivity
  • Crucibles and containers for high purity molten metals
  • Tools and refractories for glass forming which provide non-wetting, non-B2O3 containing contacts
  • Radar components and antenna windows which require exacting electrical and thermal properties
Mechanical Grades
PCBN7000
PCBN8000
Grade ZSBN
General Properties
Grade PCBN7000 combines the thermal performance and machinability of hot-pressed boron nitride with the strength and toughness of Zirconia. Its properties make it ideal for molten metal applications, also offering mechanical durability and superior electrical insulation.
Applications
  • Break Rings 
  • Crucibles & Containers
  • Jigs
  • High temperature bearings
  • High temperature valves
  • Molds
  • Nozzles
  • Heat treatment fixtures
General Properties
Grade PCBN8000 combines the thermal performance and machinability of hot-pressed boron nitride with the strength and toughness of Silicon Nitride. Its properties make it ideal for molten metal applications, also offering mechanical durability and superior electrical insulation.
Applications
  • Break Rings
  • Crucibles & Containers
  • Jigs
  • High temperature bearings
  • High temperature valves
  • Molds
  • Nozzles
  • Heat treatment fixtures
General Properties
Grade ZSBN boron nitride is a composite material combining the best thermal performance and machinability characteristics of hot-pressed boron nitride with the strength, wear-resistance, and non-reactivity of silicon carbide and zirconia. It was developed for demanding applications requiring the combination of thermal conductivity, high wear resistance, and corrosion resistance.

Originally developed for break rings for horizontal continuous casters, its unique thermal, chemical, electrical, wear, and machinability properties permit a wide variety of molten metal contact applications. Hexagonal Boron Nitride (hBN) is an inherently soft material. However, with ZSBN’s hard zirconia particles evenly dispersed with boron nitride platelets in the hard borosilicate glass matrix, it has great wear-resistant properties in addition to the inherent non-wetting aspects of the hBN.

ZSBN is a uniquely high-performing solid that is especially suited for molten metal applications such as continuous casting break rings, where wear-resistance and thermal conductivity are essential. Other applications include molten metal atomizing nozzles, glass contact wear components, and countless guides and rollers in diverse light metal baths of Zn, Mg, Al, and Li.

Key Properties

Chemically
Unparalleled resistance to molten metal wetting due to boron nitride content.
Thermally
Excellent high temperature operation and thermal shock resistance.
Mechanically
Excellent wear-resistance and increased strength from zirconia and a small amount of silicon carbide. Remarkable corrosion-resistance over a wide range of temperatures.
Machinability
Grade ZSBN is easily machined, even to complex shapes and forms, quickly and inexpensively. Machining tolerances of 0.002” or better are achievable.
Applications
  • Break rings for continuous casting of metals
  • Components
  • Crucibles
  • Deck plates
  • Heat treatment fixtures
  • High temperature bearings
  • High temperature mechanical components
  • High temperature valves
  • Jigs
  • Molds
  • Molten metal and glass castings
  • Muffles
  • Nozzles for transfer or atomization
  • Side dams
  • Spacers
Boron Nitride Properties
Mechanical Properties
Thermal Properties
Electrical Properties
Pure GradesBinder / Composite GradesMechanical Grades
PropertyUnitPCBN1000PCBN3000PCBN6000PCBN11000Grade AX05PCBN2000PCBN4000PCBN5000PCBN9000Grade AGrade HPGrade M26PCBN7000PCBN8000Grade ZSBN
Densityg/cm31.91.9 1.6 1.91.92.11.85-2.052.0 1.92.02.02.12.92.32.9
Compressive StrengthMPa40 ∥ / 40 ⊥24 ∥ –22 ∥ / 23 ⊥25 ∥312 ∥ / 312 ⊥95 ∥52 ∥ / 60 ⊥143 ∥ / 186 ⊥96 ∥170 ∥ / 170 ⊥270 ∥ / 315 ⊥219 ∥ / 254 ⊥
Flexural StrengthMPa13 ∥ / 29 ⊥21 ∥ / 20 ⊥ 28 10 ∥ / 8 ⊥22 ∥ / 21 ⊥>49 ∥ / 49 ⊥58 ∥ / 44 ⊥61 ∥ / 33 ⊥ 45 ∥ / 35 ⊥94 ∥ / 65 ⊥59 ∥ / 45 ⊥62 ∥ / 34 ⊥120 ∥ / 80 ⊥120 ∥ / 95 ⊥144 ∥ / 107 ⊥
Young’s ModulusGPa45 ∥ / 73 ⊥ 12 23 ∥ / 20 ⊥17 ∥ / 71 ⊥39 ∥ / 58 ⊥30 ∥ / 25 ⊥47 ∥ / 74 ⊥40 ∥ / 60 ⊥45 ∥ / 30 ⊥45 ∥ / 30 ⊥71 ∥ / 71 ⊥

Note: ∥ = Parallel and ⊥ = Perpendicular
Pure GradesBinder / Composite GradesMechanical Grades
PropertyUnitPCBN1000PCBN3000PCBN6000PCBN11000Grade AX05PCBN2000PCBN4000PCBN5000PCBN9000Grade AGrade HPGrade M26PCBN7000PCBN8000Grade ZSBN
Thermal ConductivityW/mK21 ∥ / 21 ⊥73 ∥ / 128 ⊥ 60 20 ∥ / 30 ⊥78 ∥ / 130 ⊥27 ∥ / 29 ⊥11 ∥ / 26 ⊥33 ∥ / 35 ⊥30 ∥ / 34 ⊥27 ∥ / 29 ⊥11 ∥ / 29 ⊥28 ∥ / 38 ⊥27 ∥ / 45 ⊥24 ∥ / 34 ⊥
Max Temp (Oxidizing) 1°C850850 850900 85085085010009008508501000+900900850
Max Temp (Inert) 1°C20002000 21002000 20001000120010001500120011501000+180018001600
CTE2 25°C ➞ 400°C 10-6/K -2.3 ∥ / -0.7 ⊥ -0.61.0 ∥ / 0.5 ⊥ -2.3 ∥ / -0.7 ⊥ 0.6 ∥ / 0.4 ⊥ 3.0 ∥ / 0.4 ⊥4.0 ∥ / 3.0 ⊥ 3.0 ∥ / 3.0 ⊥0.6 ∥ / 0.4 ⊥3.0 ∥ / 0.4 ⊥8.0 ∥ / 4.0 ⊥4.6 ∥ / 2.5 ⊥ 4.1 ∥ / 3.4 ⊥
CTE2 400°C ➞ 800°C 10-6/K -2.5 ∥ / 1.1 ⊥ – – -2.5 ∥ / 1.1 ⊥ 1.1 ∥ / 0.8 ⊥ 5.6 ∥ / 4.3 ⊥ 2.0 ∥ / 1.4 ⊥1.1 ∥ / 0.8 ⊥2.5 ∥ / 0.1 ⊥ 5.6 ∥ / 4.3 ⊥
CTE2 800°C ➞ 1200°C 10-6/K 1.6 ∥ / 0.4 ⊥ – – 1.6 ∥ / 0.4 ⊥ 1.5 ∥ / 0.9 ⊥ 7.2 ∥ / 5.2 ⊥ 1.9 ∥ / 1.8 ⊥1.5 ∥ / 0.9 ⊥3.0 ∥ / 0.1 ⊥ 7.2 ∥ / 5.2 ⊥ 
CTE2 1200°C ➞ 1600°C 10-6/K 0.9 ∥ / 0.3 ⊥ – – 0.9 ∥ / 0.3 ⊥ 2.8 ∥ / 2.7 ⊥ 4.6 ∥ / 3.4 ⊥ 5.0 ∥ / 4.8 ⊥2.8 ∥ / 2.7 ⊥ 4.6 ∥ / 3.4 ⊥
CTE2 1600°C ➞ 1900°C 10-6/K 0.5 ∥ / 0.9 ⊥ – – 0.5 ∥ / 0.9 ⊥ 7.2 ∥ / 6.1 ⊥
CTE2 25°C ➞ 1000°C 10-6/K 5.5 ∥ / 1 ⊥ – – –2.5 ∥ / 2.0 ⊥
Pure GradesBinder / Composite GradesMechanical Grades
PropertyUnitPCBN1000PCBN3000PCBN6000PCBN11000Grade AX05PCBN2000PCBN4000PCBN5000PCBN9000Grade AGrade HPGrade M26PCBN7000PCBN8000Grade ZSBN
Dielectric StrengthkV/mm>40>40>406379>40>40 10088>10661003.5
Dielectric Constant1 MHz4.0 ∥ / 4.0 ⊥4.94.0 ∥ / 4.0 ⊥4.3 ∥ / 4.0 ⊥4.5 ∥ / 3.8 ⊥ –4.6 ∥ / 4.2 ⊥4.3 ∥ / 4.0 ⊥4.5 ∥ / 3.8 ⊥18 ∥ / 19 ⊥
Dissipation Factor1 MHz1.2E-3 ∥ / 3.0E -41.0E -31.2E-3 ∥ / 3.0E-31.5E -3 ∥ / 2.1E -31.7E -3 ∥ / 6.7E -3 –1.2E-3 ∥ / 3.4E-31.5E-3 ∥ / 2.1E-31.7E-3 ∥ / 6.7E-34.5E-2 ∥ / 6.7E-2
Volume Resistivity @25°C ohm-cm>1014 / 1014 >1013 ∥ / 10141015>1015 >1013 ∥ / 1014 >1013 ∥ / 1013 >1013 ∥ / 1014 >1015 ∥ / 1015 ⊥>1013 ∥ / 1014 >1013 ∥ / 1013 >1013 ∥ / 1014>1012 ∥ / 1012 ⊥>1015 ∥ / 1015 ⊥ >1013 ∥ / 1012
Boron nitride processing
Hexagonal boron nitride can be processed into highly complex geometric shapes with very small tolerances. Longci has 3-axis, 4-axis, and 5-axis CNC machining capabilities, and has over 20 years of experience in customized boron nitride component manufacturing.
Product application
Boron Nitride (BN) is one of the few materials that offers electrical insulation and high thermal conductivity. This makes BN extremely useful in high power electronic applications in heat sink and heat spreader applications. Other materials that are commonly used are Aluminum Nitride, beryllium oxide, and sometimes Alumina – however, all of these materials are significantly more difficult to machine into intricate shapes.
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